Was picking up some Maxima to make bass leaders (
per this discussion). I didn't grab any 10lb because I knew I had a spool that was sitting in my fishing cabinet. But after digging it out, it occurred to me that this spool has to be like 5+ years old. And that got me thinking, does mono degrade just sitting in a dark drawer? I know UV light breaks it down, hence the advice to replace it regularly if you use it on a gear rod. But what about if it isn't outdoors and just sits in storage?
I mean shit, I got spools of tippet I've been using for years. And the reason I have this 10lb Maxima is for winter fishing level leaders. I don't recall it giving me problems by breaking.
This one is in my wheelhouse.......
The answer is no, nylon mono will not degrade just sitting in a dark drawer. Nylon (polyamide) is one of the most inert polymers and very chemical and hydrolysis resistant.
Nylon mono is generally a blend of types of nylon, usually nylon 6 and 6,6; and maybe a reacted alloy of the 2, nylon 6/6,6. Along with the extrusion process the chemistry dictates the key properties such as hardness, tensile strength, elongation, toughness, stiffness, and limpness, each manufacturer's secret sauce. These relate to things important to anglers such as abrasion resistance, knot strength, stretch, durability etc.
Nylons do absorb moisture, to equilibrium with the atmospheric conditions over time, of 2-4%. Moisture in nylon serves as a plasticizer making the nylon less stiff, less brittle, and more tough. Any mono you buy or have in a drawer reached equilibrium moisture long before you got it and you're not likely to notice moisture related change over time.
UV absolutely degrades nylon mono. UV exposure reduces the molecular weight as the UV light breaks bonds, called chain scission, turning long spaghetti noodle molecules into macaroni noodles. Chain scission drastically reduces the tensile strength of your mono.
Heat is another element that will affect your mono performance. Nylon is semi-crystalline, its morphology. The key temp is 117F, that's the glass-transition temp of nylon 6. If your mono goes above that temp, say in the trunk of your car or in a tackle box in the sun, the morphology changes and the mono will relax. When the temp goes back below 117F the mono takes on the shape of the spool never to recover to a useful fishing line. The same thing may happen over time sitting in your drawer but can be easily straightened one time with a small amount of stretching.
The manufacturers throw in some other stuff such as dyes and pigments that can and do have an effect on long term performance. The high end manufacturers do long term stability testing of their mono with the additive package. Some are (much) better than others......
I have miles of mono on bulk spools that's been stored in dark containers for >30 yrs. It performs exactly the same as it did 1 month after being extruded during formulation trials for that brand's development.
Pull out that spool of Maxima (or other), tie your best knots, give em a yank or a pull, and if it spools and casts well, use it with confidence. If the knots seem to break easily or you can't get a coil out of it, go get yourself a new spool of line.
Slimy